DIAMAGNETIC CORRECTIONS

VALUES OF χD FOR ANIONS
AnionχD/(1*10-6cm3mol-1)
Br--34.6
Cl--23.4
CN--13.0
CO32--28.0
F--9.1
I--50.6
NO3--18.9
NCS--31.0
OAc--31.5
OH--12.0
PO33--42
SO32--38
SO42--40.1

 

VALUES OF χD FOR COMMON LIGANDS
LigandχD/(1*10-6cm3mol-1)
Bipy-105
CO-10
C5H5--65
En-46.5
H2O-13
NH3-18
PPh3-167
Pyridine-49

 

VALUES OF χD FOR CATIONS
CationχD/(1*10-6cm3mol-1)
Ag+-28
Al3+-2
Ba2+-26.5
Ca2+-10.4
Cr2+-15
Cr3+-11
Cu+-12
Cu2+-11
Fe2+-13
Fe3+-10
H+0
Hg2+-40.0
K+-14.9
Li+-1.0
Mg2+-5.0
Mn2+-14
Mn3+-10
NH4+-13.3
Na+-6.8
Pb2+-32.0
Sn2+-20
Sn4+-16
Sr2+-19.0
Zn2+-15.0
Values obtained from: Journal of Chemical Education - Vol. 85 No. 4 April 2008

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