DIAMAGNETIC CORRECTIONS
VALUES OF χD FOR ANIONS |
Anion | χD/(1*10-6cm3mol-1) |
Br- | -34.6 |
Cl- | -23.4 |
CN- | -13.0 |
CO32- | -28.0 |
F- | -9.1 |
I- | -50.6 |
NO3- | -18.9 |
NCS- | -31.0 |
OAc- | -31.5 |
OH- | -12.0 |
PO33- | -42 |
SO32- | -38 |
SO42- | -40.1 |
VALUES OF χD FOR COMMON LIGANDS |
Ligand | χD/(1*10-6cm3mol-1) |
Bipy | -105 |
CO | -10 |
C5H5- | -65 |
En | -46.5 |
H2O | -13 |
NH3 | -18 |
PPh3 | -167 |
Pyridine | -49 |
VALUES OF χD FOR CATIONS |
Cation | χD/(1*10-6cm3mol-1) |
Ag+ | -28 |
Al3+ | -2 |
Ba2+ | -26.5 |
Ca2+ | -10.4 |
Cr2+ | -15 |
Cr3+ | -11 |
Cu+ | -12 |
Cu2+ | -11 |
Fe2+ | -13 |
Fe3+ | -10 |
H+ | 0 |
Hg2+ | -40.0 |
K+ | -14.9 |
Li+ | -1.0 |
Mg2+ | -5.0 |
Mn2+ | -14 |
Mn3+ | -10 |
NH4+ | -13.3 |
Na+ | -6.8 |
Pb2+ | -32.0 |
Sn2+ | -20 |
Sn4+ | -16 |
Sr2+ | -19.0 |
Zn2+ | -15.0 |
Values obtained from: Journal of Chemical Education - Vol. 85 No. 4 April 2008