INDICATORS

View Introduction to Acid-Base Titrations & Indicator Theory

ACID-BASE INDICATORS
IndicatorColour ChangeIntervalPreparation
Malachite green oxalateYellow / Green-blue0.0 - 2.00.1g in 100ml water
Brilliant greenYellow / Green0.0 - 2.60.1g in 100ml water
Eosin yellowishYellow / Fluorescent green0.0 - 3.00.1g in 100ml water
Erythrosin BOrange / Red0.0 - 3.60.1g in 100ml water
Methyl greenYellow / Blue0.1 - 2.30.1g in 100ml water
Methyl violetYellow / Violet0.1 - 2.70.1g in 100ml ethanol (20%)
Picric acidColourless / Yellow 0.2 - 1.00.1g in 100ml ethanol (20%)
Cresol redRed / Yellow0.2 - 1.80.1g in 100ml ethanol (20%)
Crystal violetYellow / Blue-violet0.8 - 2.60.1g in 100ml ethanol (70%)
m-Cresol purpleRed / Yellow1.2 - 2.80.04g in 100ml ethanol (20%)
Thymol blueRed / Yellow1.2 - 2.80.04g in 100ml ethanol (20%)
p-Xylenol blueRed / Yellow1.2 - 2.80.1g in 100ml ethanol (50%)
Eoisin bluishColourless / Fluorescent pink1.4 - 2.4 0.1g in 100ml water
Quinaldine redColourless / Pink1.4 - 3.20.1g in 100ml ethanol (60%)
2,4-DinitrophenolColourless / Yellow2.8 - 4.70.1g in 100ml ethanol (70%)
4-(Dimethylamino)azobenzeneRed / Yellow-orange2.9 - 4.00.3g in 100ml ethanol (90%)
Bromochlorophenol blueYellow / Blue-violet3.0 - 4.6 0.1g in 100ml ethanol (20%)
Bromophenol blueYellow / Blue-violet3.0 - 4.60.1g in 100ml ethanol (20%)
Congo redBlue / Yellow-orange3.0 - 5.20.2g in 100ml water
Methyl orangeBlue / Yellow-orange3.1 - 4.40.04g in 100ml ethanol (20%)
Methyl orange solutionRed / Yellow-orange3.1 - 4.40.04g in 100ml ethanol (20%)
Bromocresol greenYellow / Blue 3.8 - 5.40.1g in 100ml ethanol (20%)
2,5-DinitrophenolColourless / Yellow4.0 - 5.80.07g in 100ml ethanol (70%)
Alizarinsulfonic acid sodium saltYellow / Violet4.3 - 6.30.1g in 100ml ethanol (50%)
Methyl redRed / Yellow-orange4.4 - 6.20.1g in 100ml ethanol (96%)
Methyl red sodium saltRed / Yellow-orange4.4 - 6.2 0.1g in 100ml water
Chlorophenol redYellow / Purple4.8 - 6.40.1g in 100ml ethanol (20%)
Bromocresol purpleYellow / Purple5.2 - 6.80.1g in 100ml ethanol (20%)
Bromophenol redOrange-yellow / Purple5.2 - 6.80.1g in 100ml ethanol (20%)
4-NitrophenolColourless / Yellow5.4 - 7.50.2g in 100ml ethanol (96%)
Bromoxylenol blueYellow / Blue 5.7 - 7.50.1g in 100ml ethanol (96%)
AlizarinYellow / Red5.8 - 7.20.5g in 100ml ethanol (96%)
Bromothymol blueYellow / Blue6.0 - 7.60.1g in 100ml ethanol (20%)
Phenol redYellow / Red-violet6.4 - 8.20.1g in 100ml ethanol (20%)
3-NitrophenolColourless / Yellow-orange6.6 - 8.60.3g in 100ml ethanol (96%)
Neutral redBlue-red / Orange-yellow6.8 - 8.00.3g in 100ml ethanol (70%)
4,5,6,7-TetrabromophenolphthaleinColourless / Purple7.0 - 8.00.1g in 100ml ethanol (96%)
Cresol redOrange / Purple7.0 - 8.80.1g in 100ml ethanol (50%)
1-NaphtolphthaleinBrown - Blue-green7.1 - 8.30.1g in 100ml ethanol (96%)
Cresol purpleYellow / Purple7.4 - 9.00.04g in 100ml ethanol (20%)
Thymol blueYellow / Blue8.0 - 9.60.04g in 100ml ethanol (20%)
p-Xylenol blueYellow / Blue8.0 - 9.60.1g in 100ml ethanol (50%)
PhenolphthaleinColourless / Red-violet8.2 - 9.80.1g in 100ml ethanol (96%)
ThymolphthaleinColourless / Blue9.3 - 10.50.1g in 100ml ethanol (50%)
Alkali blueViolet / Pink9.4 - 14.00.1g in 100ml ethanol (96%)
Alizarin yellow GGLight yellow / Brown-yellow10.0 - 12.10.1g in 100ml water
AlizarinRed / Purple10.1 - 12.10.5g in 100ml ethanol (96%)
Titan yellowYellow / Red12.0 - 13.00.1g in 100ml ethanol (20%)
Indigo carmineBlue / Yellow11.5 - 13.00.25g in 100ml ethanol (50%)
Epsilon blueOrange / Violet 11.6 - 13.0 0.1g in 100ml water

REDOX INDICATORS
Indicator  Redox potential
E0[V]        Em[V]
(pH=0)     (pH=7)
20oC         30oC
rHColour change
oxidised form
Preparation
Amido black 10 B+0.57      +0.84 Yellow-brown / Blue0.2g in 100ml water
2,2'-Bipyridin (iron(II) complex)+1.03 Pale blue / Red0.695g FeSO4.7H2O & 1.171g 2,2'-bipyridin in 100ml water
Brilliant cresyl blue+0.58      +0.05 Blue / Colourless0.5g in 100ml water
2,6-Dichlorophenolindophenol sodium salt (dihydrate)+0.67      +0.2322Blue / Colourless0.02g in 100ml water
3,3'-Dimethylnaphthidine+0.78 Purple-red / Colourless 1.0g in 100ml glacial acetic acid
N,N-Dimethyl-1,4-phenylenediammonium dichloride+0.75 Dark blue / Colourless0.2g in 100ml water
Diphenylamine+0.76 Blue-violet / Colourless1.0g in 100ml sulphuric acid (96%)
Ferroin
(1,10-Phenanthroline iron(II) complex)
+1.0640Blue / Orange-red 
Indigo carmine
(Indigo disulfonate disodium salt)
+0.29      -0.1110Blue / Yellow0.05g in 100ml water
Methylene blue+0.53      +0.01
(30oC)
14.5Blue / Colourless0.3g in 100ml water
Neutral red+0.24      -0.293Violet-red / Colourless0.05g in 100ml ethanol (96%)
Nile blue (sulphate)+0.41      -0.12 Blue-red / Colourless0.1g in 100ml water
1,10-Phenanthroline (monohydrate)+1.14      +1.06 Pale blue / Red0.695g FeSO4.7H2O & 1.487g 1,10-Phenanthroline in 100ml water
N-Phenylanthranilic acid+0.89 Purple-red / Colourless 0.1g in 5ml 0.1M NaOH; make up to 100ml with water
Safranin+0.24      -0.294Blue-violet / Colourless0.05g in 100ml water
Thionine+0.56      +0.0616Violet / Colourless0.05g in 100ml ethanol (60%)
Variamine blue salt B+0.71      +0.31 Blue-violet / Colourless1.0g in 100ml water

Charts & Tables