WEB TUTORIAL - Group Theory
Interpreting Results
Now that the Reduction Forumla has given us the A1 and B1 representations we have to check the Character Table for Normal and Quadratic Terms to determine whether the A1 and B1 representations will be IR or Raman active.
Number of symmetry elements, h = 4
C2v E C2 (z) v(xz) v(yz) Linear functions,
rotationsQuadratic
functionsCubic
functionsA1 +1 +1 +1 +1 z x2, y2, z2 z3, x2z, y2z A2 +1 +1 -1 -1 Rz xy xyz B1 +1 -1 +1 -1 x, Ry xz xz2, x3, xy2 B2 +1 -1 -1 +1 y, Rx yz yz2, y3, x2y From this we see that they are both IR and Raman active. This should be reported in the style shown below:
Γstretch = A1 (IR,R) + B1 (IR,R)