WEB TUTORIAL - Group Theory

Interpreting Results

Now that the Reduction Forumla has given us the A1 and B1 representations we have to check the Character Table for Normal and Quadratic Terms to determine whether the A1 and B1 representations will be IR or Raman active.

C2vEC2 (z)sigmav(xz)sigmav(yz)Linear functions,
rotations
Quadratic
functions
Cubic
functions
A1+1+1+1+1zx2, y2, z2z3, x2z, y2z
A2+1+1-1-1Rzxyxyz
B1+1-1+1-1x, Ryxzxz2, x3, xy2
B2+1-1-1+1y, Rxyzyz2, y3, x2y
Number of symmetry elements, h = 4

From this we see that they are both IR and Raman active. This should be reported in the style shown below:

Γstretch = A1 (IR,R) + B1 (IR,R)

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