Composite Reactions & the Steady State Approximation

HALOGENATION OF PROPANONE

Hint

When summing steps in a reaction to give the overall reaction, only the net direction of reversible reactions is considered.

Thus for the reversible reaction

[Halogenation of Propanone - Mechanism A - Reversible Step]
only the (net) forward reaction
[Halogenation of Propanone - Mechanism A - Elementary Step 1]
will be considered.

Therefore, to obtain the overall reaction, the following elementary reactions need to be added (and terms appearing on both sides eliminated):

[Halogenation of Propanone - Mechanism A - Elementary Step 1]

[Halogenation of Propanone - Mechanism A - Elementary Step 3]

Confirmation that Proposed Mechanism equates to the Overall Reaction

Given that the overall reaction is

Pk + I2 → PI + H+ + I-

And that the proposed mechanism is

[Halogenation of Propanone - Mechanism A]

It can be stated that

The Proposed Mechanism does not give the Overall Reaction

The Proposed Mechanism gives the Overall Reaction