Composite Reactions & the Steady State Approximation

DECOMPOSITION OF AZOMETHANE

Hint

For an elementary reaction of the form, aA + bB → cC

[Rate of Elementary Reaction]

Note: Only the reactant concentrations appear in the rate expression (i.e., [A] and [B] for the reaction given above).

Composite or Elementary?

If the reaction

AZO → C2H6 + N2
was elementary, the rate law could be written as:

+d[N2]/dt = k[C2H6]

+d[N2]/dt = k[C2H6][N2]

+d[N2]/dt = k[AZO][C2H6][N2]

+d[N2]/dt = k[AZO]

+d[N2]/dt = k[AZO]2