Composite Reactions & the Steady State Approximation

DECOMPOSITION OF AZOMETHANE

Hint

For an elementary reaction of the form, aA + bB → cC,

[Rate of Elementary Reaction]

Example:

For the elementary reaction, O3 + NO → NO2 + O2
r = -d[O3]/dt = -d[NO]/dt = +d[NO2]/dt = + d[O2]/dt

r = k[O3]1[NO]1 = k[O3][NO]

Rate of Production of Nitrogen in the Third Elementary Step {+(d[N2]/dt)3}

For the third elementary step,

[Azomethane Mechanism (s3)]

the rate of production of Nitrogen would be

+d[N2]/dt = -k2[AZO*]

+d[N2]/dt = +k2[AZO*]

+d[N2]/dt = -k2[N2]

+d[N2]/dt = +k2[N2]

+d[N2]/dt = -k2[C2H6][N2]

+d[N2]/dt = +k2[C2H6][N2]